Unless you truly need the extra functionality in ACF, just use Core's built-in custom fields - just go to the top of the page, Screen Options, and make sure they're showing. Then carefully make sure to name the field the same thing every time. You should also be sure to create a child theme rather than editing your existing one, so your code doesn't get overwritten when your theme updates, and then make the call conditional, so if you haven't added any keywords no empty meta tag is added. This code will also allow you to add multiple keywords.
Assuming your custom field's name is meta_keywords
:
<?php
// false returns all values
$keywords = get_post_meta($post->ID, 'meta_keywords', false);
// if any were found
if(count($keywords) > 0) {
// convert the array to comma-separated string and output
$all_keywords = implode(',', $keywords); ?>
<meta name="keywords" content="<?php echo $all_keywords; ?>"><?php
}
// otherwise don't output meta keywords tag at all
?>